2025-04-15
I. Key Characteristics of Thermally Conductive Plastics
1. Performance Advantages
Weight Advantage: With a density only two-thirds that of aluminum alloys, they significantly enhance product lightweighting.
Molding Efficiency: Utilize injection molding processes, eliminating post-processing steps in traditional metal machining and shortening production cycles.
Cost-Effectiveness: Superior price-performance ratio due to processing efficiency, material weight reduction, and eco-friendliness.
Environmental Benefits: Cleaner production processes, recyclability, and lower carbon footprint compared to metals and ceramics.
Design Flexibility: Enable complex geometries and thin-walled structures for diverse applications.
Electrical Safety: Combine thermal conductivity with excellent insulation, ideal for non-isolated power supplies.
Chemical Stability: Outstanding corrosion resistance for long-term use in harsh environments.
2. Performance Comparison
II. Thermal Theory and Heat Dissipation Design
1. Heat Transfer Mechanisms
1. Convection:
- Follows Newton’s cooling law, relying on fluid (e.g., air) movement. Forced convection (e.g., fans) enhances heat exchange.
2. Conduction:
- Efficiency depends on:
- Effective contact area
- Material thickness
- Thermal conductivity (λ)
(Metals traditionally dominate here)
3. Radiation:
- Infrared radiation (8–14 μm wavelength) transfers energy, influenced by:
- Heat sink geometry
- Effective radiation surface area
- Material emissivity
2. Thermal Resistance Model
Total system thermal resistance (Rj1–Rj5) is a series sum. Thermally conductive plastics optimize two critical resistances:
Rj3 (substrate material resistance)
Rj5 (heat sink-air interface resistance)
3. Critical Thermal Conductivity Threshold
When λ > 5 W/m·K and thickness < 5 mm, convection dominates, allowing plastics to match metal performance.
4. Plastic vs. Metal Thermal Conductivity
Traditional View: Metals (e.g., aluminum, λ≈200 W/m·K) dominate LED heat sinks, while plastics (λ<1 W/m·K) fail.
Key Findings:
1. Low λ (<5 W/m·K): Conventional plastics (λ<1 W/m·K) underperform.
2. Breakthrough Range (λ≥5 W/m·K + thickness<5 mm): Convection-driven, λ impact diminishes.
3. Substitution Feasibility: Plastics with λ≥20 W/m·K (1/10 of metals) and <5 mm heat-source distance achieve comparable performance.
Innovation: Thermally conductive plastics (λ≥5 W/m·K + thin-wall design) disrupt metal-dependent paradigms.
III. Material Composition and Selection
1. Thermal Fillers
Metallic: Electron-driven (e.g., Cu/Al powder) – efficient but conductive.
Non-Metallic: Phonon-driven (e.g., Al₂O₃, BN) – electrically insulating.
2. Filler Performance Comparison
3. Matrix and Formulation
Polymers: PPS, PA6/66, LCP, PC – balance temperature resistance, processability, and cost.
Performance Types:
Insulating: Oxide/nitride fillers (e.g., Al₂O₃ + PA6).
Conductive: Metal/graphite fillers (e.g., carbon + PA).
IV. Market Overview and Products
1. Global Brands
SABIC: DTK22, OX11315, OX10324, PX11311U, PX11313, PX13322, PX13012, PX10323
Envalior: D5506, D3612, Stanyl-TC154/155, TKX1010D, D8102, Stanyl-TC153
Celanese: D5120
2. Material Selection Criteria
Thermal Performance: High-λ fillers (BN/SiC for demanding applications).
Electrical Safety: Insulating fillers (Al₂O₃/BN).
Moldability: High-flow polymers (e.g., nylon) for complex parts.
Cost: Al₂O₃ is cost-effective; BN is premium.
3. Industry Innovations
Material R&D: High-filler, low-viscosity composites (nanofiller technology).
Performance Breakthroughs: Insulating plastics achieving λ>5 W/m·K.
4. Market Outlook
Driven by 5G, EVs, and Mini LED adoption, demand grows for lightweight thermal solutions (e.g., automotive electronics, wearables).